Research Article | Open Access Volume 15| Issue 3 | Page 60-64 | https://doi.org/10.15228/2025.v15.i3.p10 |
Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes
J. Lipkowski
Ningbo University of Technology, China-CEEC Innovation Cooperation Research Center, Ningbo, Zhejiang, China,
K. Suwinska
Faculty of Mathematical and Natural Sciences, Cardinal Stefan Wyszynski University in Warsaw, Poland
M. Khalaj
Department of Chemistry, Buinzahra Branch, Islamic Azad University Buinzahra, Iran
| Received 10 Apr, 2025 | Accepted 20 Apr, 2025 | Published 30 Apr, 2025 |
Structural transformations of hexagonal clathrate lattices formed by Ni (NCS)2(4-methylpyridine)4 with benzene derivatives occurring at temperature variations were determined and discussed. The guest species was found to influence the observed phenomena significantly. Two isomers of bromo nitrobenzene (ortho and meta) and meta-dinitrobenzene were used. The clathrates, hexagonal at room temperature, undergo significant changes at lower temperatures, which is associated with a consecutive order of the guest molecules. Apparent structural deformations of the 1-bromonaphthalene guest molecule were measured and discussed based on its orientational disordering at varying temperatures.
How to Cite this paper?
APA-7 Style
J. Lipkowski, K. Suwinska & M. Khalaj (2025). Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes. Pakistan Journal of Chemistry, 15(3), 60-64. https://doi.org/10.15228/2025.v15.i3.p60-64.
ACS Style
Lipkowski. J; Suwinska. K & Khalaj. M; Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes. Pakistan Journal of Chemistry, 15(3), 60-64. https://doi.org/10.15228/2025.v15.i3.p60-64.
AMA Style
Lipkowski. J., Suwinska. K. & Khalaj. M. “Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes.” Pakistan Journal of Chemistry, 15(3), 60-64. https://doi.org/10.15228/2025.v15.i3.p60-64.
Chicago/Turabian Style
Lipkowski J, Suwinska K & Khalaj M, Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes 2025 Pakistan Journal of Chemistry, 15(3), 60-64. https://doi.org/10.15228/2025.v15.i3.p60-64.
This work is licensed under a Creative Commons Attribution 4.0 International License.