Pakistan Journal of Chemistry

Research Article | Open Access

Influence of Ionic Strength on Thionine Degradation by UV/Visible Radiation With Maltose

M. Yamin

Laboratory of Thermodynamics of Proteins-Biochemistry-Biology, University of Campinas, UNICAMP, Campinas, SP, Brazil

F. Rehman

Laboratory of Thermodynamics of Proteins-Biochemistry-Biology, University of Campinas, UNICAMP, Campinas, SP, Brazil

K. Ahmed

Interdisciplinary Research Centre in Biomedical Materials (IRCBM), COMSATS, University Islamabad, Lahore, Pakistan

 

Received
21 May, 2020
Accepted
13 Oct, 2020
Published
07 Jun, 2021

 

Degradation of thionine (Th) was observed with UV/visible spectrophotometer at λmax 599 nm using maltose as a reductant in aerobic conditions. A significant role of ionic strength by changing the concentration of nitrate ions was observed, leading to more rapid degradation of dye at increasing concentration than low concentration, which was confirmed by measuring the optical density of the reaction mixture. Rate constant at elevated temperature showed that reaction depends upon ionic strength and temperature that follows pseudo-first-order kinetics. Activation parameters like Ea , ΔG*, ΔS* and ΔH* were computed, and a mechanism of reduction of dye was proposed.

How to Cite this paper?

APA-7 Style
Yamin, M., Rehman, F., Ahmed, K. (2020). Influence of Ionic Strength on Thionine Degradation by UV/Visible Radiation With Maltose. Pakistan Journal of Chemistry, 10(1-4), 24-34. https://doi.org/10.15228/2020.v10.i01-4.p04

ACS Style
Yamin, M.; Rehman, F.; Ahmed, K. Influence of Ionic Strength on Thionine Degradation by UV/Visible Radiation With Maltose. Pak. J. Chem. 2020, 10, 24-34. https://doi.org/10.15228/2020.v10.i01-4.p04

AMA Style
Yamin M, Rehman F, Ahmed K. Influence of Ionic Strength on Thionine Degradation by UV/Visible Radiation With Maltose. Pakistan Journal of Chemistry. 2020; 10(1-4): 24-34. https://doi.org/10.15228/2020.v10.i01-4.p04

Chicago/Turabian Style
Yamin, M., F. Rehman, and K. Ahmed. 2020. “Influence of Ionic Strength on Thionine Degradation by UV/Visible Radiation With Maltose” Pakistan Journal of Chemistry 10, no. 1-4: 24-34. https://doi.org/10.15228/2020.v10.i01-4.p04