Pakistan Journal of Chemistry

Research Article | Open Access
Volume 2 | Issue 1 | Paper 06 |  https://doi.org/10.15228/2012.v02.i01.p06

Rapid and Inexpensive Densitometric Method, Using TLC Plates, for Quantification and Determination of Nine Pesticides in Water

M. Hamada

Al Azhar University Gaza, Faculty of Science, Department of Chemistry, Gaza Strip, Palestine

N. A. Ghalwa

Al Azhar University Gaza, Faculty of Science, Department of Chemistry, Gaza Strip, Palestine

H.M. Abu-Shawish

Al Azhar University Gaza, Faculty of Science, Department of Chemistry, Gaza Strip, Palestine

O. Shubair

Al Azhar University Gaza, Faculty of Science, Department of Chemistry, Gaza Strip, Palestine

Received
07 Mar, 2012
Accepted
07 Jun, 2012
Published
07 Dec, 2012

ABSTRACT:

Nine pesticides of commonly used in Gaza Strip were tested in this work for optimal separation onto silica gel TLC plates in acetone/ cyclohexane, 1:2 (v/v), as a mobile phase to develop a new densitometric method for quantification and determination of these pesticides in water samples. These pesticides are: abamectine, atrazine, benomyl, cymoxanil, diuron, imidacloprid, linuron, penconazole, and propazine. Calibration plots were linear between 25 to 1000 ng/spot for all pesticides with a correlation coefficient, r, between 0.9920 and 0.9993. Recoveries after enrichment of real water samples on Bakerbond RP-C18cartridges were between 79.4 and 103.7 % at a relative standard deviation between ± 1.92 and 3.68 %. Detection limits LOD of 25 – 100 ng per spot for eight of the pesticides were reached, which meet the European limits for pesticides in drinking water (100 ngL-1 ), while penconazole has an LOD value of 200 ngL-1 because of its low UV-absorption coefficient.

How to Cite this paper?

APA-7 Style
Hamada, M., Ghalwa, N.A., Abu-Shawish, H.M., Shubair, O. (2012). Rapid and Inexpensive Densitometric Method, Using TLC Plates, for Quantification and Determination of Nine Pesticides in Water
Pakistan Journal of Chemistry, 2(1), 34-40. https://doi.org/10.15228/2012.v02.i01.p06

ACS Style
Hamada, M.; Ghalwa, N.A.; Abu-Shawish, H.M.; Shubair, O. Rapid and Inexpensive Densitometric Method, Using TLC Plates, for Quantification and Determination of Nine Pesticides in Water
Pak. J. Chem. 2012, 2, 34-40. https://doi.org/10.15228/2012.v02.i01.p06

AMA Style
Hamada M, Ghalwa NA, Abu-Shawish HM, Shubair O. Rapid and Inexpensive Densitometric Method, Using TLC Plates, for Quantification and Determination of Nine Pesticides in Water
Pakistan Journal of Chemistry. 2012; 2(1): 34-40. https://doi.org/10.15228/2012.v02.i01.p06

Chicago/Turabian Style
Hamada, M., N. A. Ghalwa, H. M. Abu-Shawish, and O. Shubair. 2012. “Rapid and Inexpensive Densitometric Method, Using TLC Plates, for Quantification and Determination of Nine Pesticides in Water
” Pakistan Journal of Chemistry 2, no. 1: 34-40. https://doi.org/10.15228/2012.v02.i01.p06