Research Article | Open Access Volume 3 | Issue 1 | Paper 03 | doi.org/10.15228/2013.v03.i01.p03 |
A.H. Banday
Department of Chemistry, Islamia College of Science and Commerce, Srinagar-190009, J&K, India
| Received 12 Aug, 2012 | Accepted 17 Jan, 2013 | Published 05 Feb, 2013 |
ABSTRACT:
An efficient, facile and regioselective synthesis of α,β-unsaturated aldehydes from β-hydroxynitriles is reported. The reaction is carried out using DIBAL-H and promoted by piperidine under dry conditions at a temperature of -78 oC and can be described as a concomitant reduction-elimination reaction. The same reaction if carried out in the absence of piperidine gives mainly the uneliminated reduction product. The products formed are of immense importance as synthons in a large number of chemical reactions and biological processes.
How to Cite this paper?
APA-7 Style
Banday, A.H. (2013). Piperidine Promoted Regioselective Synthesis of α, β-unsaturated Aldehydes. Pakistan Journal of Chemistry, 3(1), 19-22. https://doi.org/10.15228/2013.v03.i01.p03
ACS Style
Banday, A.H. Piperidine Promoted Regioselective Synthesis of α, β-unsaturated Aldehydes. Pak. J. Chem. 2013, 3, 19-22. https://doi.org/10.15228/2013.v03.i01.p03
AMA Style
Banday AH. Piperidine Promoted Regioselective Synthesis of α, β-unsaturated Aldehydes. Pakistan Journal of Chemistry. 2013; 3(1): 19-22. https://doi.org/10.15228/2013.v03.i01.p03
Chicago/Turabian Style
Banday, A., H.. 2013. “Piperidine Promoted Regioselective Synthesis of α, β-unsaturated Aldehydes” Pakistan Journal of Chemistry 3, no. 1: 19-22. https://doi.org/10.15228/2013.v03.i01.p03
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