{"id":8096,"date":"2025-04-29T21:10:32","date_gmt":"2025-04-29T21:10:32","guid":{"rendered":"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/?p=8096"},"modified":"2025-05-08T18:36:56","modified_gmt":"2025-05-08T18:36:56","slug":"pjc-1025","status":"publish","type":"post","link":"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2025\/04\/29\/pjc-1025\/","title":{"rendered":"Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"8096\" class=\"elementor elementor-8096\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-0f4eb05 e-flex e-con-boxed e-con e-parent\" data-id=\"0f4eb05\" data-element_type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-45bd30d e-con-full e-flex e-con e-child\" data-id=\"45bd30d\" data-element_type=\"container\">\n\t\t\t\t<div class=\"elementor-element elementor-element-d1af79a elementor-widget elementor-widget-text-editor\" data-id=\"d1af79a\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<table border=\"0\" width=\"100%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\"><tbody><tr><td><div><strong>Research Article | Open Access<\/strong><\/div><div class=\"item doi\"><span class=\"value\">Volume 15| Issue 3 | Page 60-64 | <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2025\/04\/PJC.v15.i03.p10.pdf\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.15228\/2025.v15.i3.p10<\/a><\/span><\/div><\/td><\/tr><\/tbody><\/table><h4><strong><b>Fine Intermolecular Interactions in Clathrates Formed by MX<\/b><\/strong><strong><sub><b>2<\/b><\/sub><\/strong><strong><b>A<\/b><\/strong><strong><sub><b>4 <\/b><\/sub><\/strong><strong><b>Host Complexes<\/b><\/strong><\/h4><p><a href=\"https:\/\/orcid.org\/0000-0002-2573-2414\"><strong>J. Lipkowski<\/strong><\/a><br \/>Ningbo\u00a0University of Technology<strong><b>, <\/b><\/strong>China-CEEC Innovation Cooperation Research Center, Ningbo, Zhejiang, China,<\/p><p><strong>K. Suwinska<\/strong><br \/>Faculty of Mathematical and Natural Sciences, Cardinal Stefan Wyszynski University in Warsaw, Poland<\/p><p><strong>M. Khalaj<\/strong><br \/>Department of Chemistry, Buinzahra Branch, Islamic Azad University Buinzahra, Iran<\/p><div class=\"row\"><div class=\"main_entry\"><table border=\"0\" width=\"93%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\"><tbody><tr><td align=\"center\" valign=\"top\"><strong>Received<\/strong><br \/>10 Apr, 2025<\/td><td align=\"center\" valign=\"top\"><strong>Accepted<\/strong><br \/>20 Apr, 2025<\/td><td align=\"center\" valign=\"top\"><strong>Published<\/strong><br \/>30 Apr, 2025<\/td><\/tr><\/tbody><\/table><div class=\"item abstract\"><p>Structural transformations of hexagonal clathrate lattices formed by Ni (NCS)<sub>2<\/sub>(4-methylpyridine)<sub>4<\/sub>\u00a0with benzene derivatives occurring at temperature variations were determined and discussed. The guest species was found to influence the observed phenomena significantly. Two isomers of bromo nitrobenzene (<em>ortho<\/em>\u00a0and <em>meta<\/em>) and <em>meta<\/em>-dinitrobenzene were used. The clathrates, hexagonal at room temperature, undergo significant changes at lower temperatures, which is associated with a consecutive order of the guest molecules. Apparent structural deformations of the 1-bromonaphthalene guest molecule were measured and discussed based on its orientational disordering at varying temperatures.<strong><b>\u00a0<\/b><\/strong><\/p><\/div><div class=\"item abstract\"><h3 class=\"label\">How to Cite this paper?<\/h3><div class=\"csl-entry\"><p><strong>APA-7 Style<\/strong><br \/>J. Lipkowski, K. Suwinska &amp; M. Khalaj (2025). Fine Intermolecular Interactions in Clathrates Formed by MX<sub>2<\/sub>A<sub>4 <\/sub>Host Complexes. <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2025\/04\/PJC.v15.i03.p10.pdf\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 15(3), 60-64.<\/a> \u00a0https:\/\/doi.org\/10.15228\/2025.v15.i3.p60-64.<\/p><p><strong>ACS Style<\/strong><br \/>Lipkowski. J; Suwinska. K &amp; Khalaj. M; Fine Intermolecular Interactions in Clathrates Formed by MX<sub>2<\/sub>A<sub>4 <\/sub>Host Complexes. <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2025\/04\/PJC.v15.i03.p10.pdf\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 15(3), 60-64.<\/a> \u00a0https:\/\/doi.org\/10.15228\/2025.v15.i3.p60-64.<\/p><p><strong>AMA Style<\/strong><br \/>Lipkowski. J.,\u00a0 Suwinska. K. &amp; Khalaj. M. &#8220;Fine Intermolecular Interactions in Clathrates Formed by MX<sub>2<\/sub>A<sub>4 <\/sub>Host Complexes.&#8221; <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2025\/04\/PJC.v15.i03.p10.pdf\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 15(3), 60-64.<\/a> \u00a0https:\/\/doi.org\/10.15228\/2025.v15.i3.p60-64.<\/p><p><strong>Chicago\/Turabian Style<\/strong><br \/>Lipkowski J, Suwinska K &amp; Khalaj M, Fine Intermolecular Interactions in Clathrates Formed by MX<sub>2<\/sub>A<sub>4 <\/sub>Host Complexes <em>2025\u00a0<\/em> <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2025\/04\/PJC.v15.i03.p10.pdf\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 15(3), 60-64.<\/a> \u00a0https:\/\/doi.org\/10.15228\/2025.v15.i3.p60-64.<\/p><\/div><\/div><div class=\"item copyright\"><p><a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\"><img decoding=\"async\" src=\"https:\/\/i.creativecommons.org\/l\/by\/4.0\/88x31.png\" alt=\"Creative Commons License\" \/><\/a><\/p><p>This work is licensed under a\u00a0<a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\">Creative Commons Attribution 4.0 International License<\/a>.<\/p><\/div><\/div><\/div>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-00a18c9 e-con-full e-flex e-con e-child\" data-id=\"00a18c9\" data-element_type=\"container\">\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Research Article | Open AccessVolume 15| Issue 3 | Page 60-64 | https:\/\/doi.org\/10.15228\/2025.v15.i3.p10 Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes J. LipkowskiNingbo\u00a0University of Technology, China-CEEC Innovation Cooperation Research Center, Ningbo, Zhejiang, China, K. SuwinskaFaculty of Mathematical and Natural Sciences, Cardinal Stefan Wyszynski University in Warsaw, Poland M. KhalajDepartment of Chemistry, Buinzahra Branch, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-8096","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes - Pakistan Journal of Chemistry<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2025\/04\/29\/pjc-1025\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes - Pakistan Journal of Chemistry\" \/>\n<meta property=\"og:description\" content=\"Research Article | Open AccessVolume 15| Issue 3 | Page 60-64 | https:\/\/doi.org\/10.15228\/2025.v15.i3.p10 Fine Intermolecular Interactions in Clathrates Formed by MX2A4 Host Complexes J. LipkowskiNingbo\u00a0University of Technology, China-CEEC Innovation Cooperation Research Center, Ningbo, Zhejiang, China, K. SuwinskaFaculty of Mathematical and Natural Sciences, Cardinal Stefan Wyszynski University in Warsaw, Poland M. 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