{"id":2864,"date":"2017-12-31T15:56:00","date_gmt":"2017-12-31T15:56:00","guid":{"rendered":"https:\/\/chempublishers.com\/pjc\/?p=2864"},"modified":"2025-06-13T13:51:50","modified_gmt":"2025-06-13T13:51:50","slug":"pjc-0417","status":"publish","type":"post","link":"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2017\/12\/31\/pjc-0417\/","title":{"rendered":"Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"2864\" class=\"elementor elementor-2864\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-f692184 e-flex e-con-boxed e-con e-parent\" data-id=\"f692184\" data-element_type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-9000113 e-con-full e-flex e-con e-child\" data-id=\"9000113\" data-element_type=\"container\">\n\t\t\t\t<div class=\"elementor-element elementor-element-d15e8e9 elementor-widget elementor-widget-text-editor\" data-id=\"d15e8e9\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<table border=\"0\" width=\"100%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td>\n<div><strong>Research Article | Open Access<\/strong><\/div>\n<div class=\"item doi\"><span class=\"value\">Volume 7 | Issue 1-4 |&nbsp;<a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2024\/12\/PJC-v07.i01-4.p04.pdf\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04<\/a><\/span><\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<article class=\"obj_article_details\">\n<h4>Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate<\/h4>\n<div class=\"row\">\n<div class=\"main_entry\">\n<p><span class=\"name\">S. Summer<\/span><\/p>\n<p>Department of Chemistry, Jinnah University for Women, V-C, Nazimabad, Karachi, Pakistan<\/p>\n<p><span class=\"name\">S. Ansari<\/span><\/p>\n<p>Department of Chemistry, Jinnah University for Women, V-C, Nazimabad, Karachi, Pakistan<\/p>\n<p><span class=\"name\">N. Qamar<\/span><\/p>\n<p>Department of Chemistry, Jinnah University for Women, V-C, Nazimabad, Karachi, Pakistan<\/p>\n<p><span class=\"name\">I.I. Naqvi<\/span><\/p>\n<p>Department of Chemistry, Jinnah University for Women, V-C, Nazimabad, Karachi, Pakistan<\/p>\n<p><\/p>\n<table border=\"0\" width=\"93%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td align=\"center\" valign=\"top\"><strong>Received<\/strong><br>12 Mar, 2017<\/td>\n<td align=\"center\" valign=\"top\"><strong>Accepted<\/strong><br>20 Jun, 2017<\/td>\n<td align=\"center\" valign=\"top\"><strong>Published<\/strong><br>25 Sep, 2017<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<div class=\"item abstract\">\n<p class=\"ql-align-justify\">Ag(I) catalyzed oxidation of tris(2,2\u2019-bipyridine)Fe(II) complex ion by peroxodisulfate has been undertaken at different temperatures (20\u00b0C-40\u00b0C). Redox reaction was investigated at different temperatures to evaluate the thermodynamic parameters of activation \u0394H<sup>#<\/sup>, \u0394S<sup>#<\/sup>&nbsp;and \u0394G<sup>#<\/sup>. The value of energy of activation (Ea) of the redox reaction was estimated from Arrhenius plot and found to be 18.316\u00b10.21 kJ\/mol. The values of thermodynamic parameters of activation such as enthalpy of activation (\u0394H<sup>#<\/sup>&nbsp;) and entropy of activation (\u0394S<sup>#<\/sup>) were consequently evaluated from Eyring plot. The Gibbs energy of activation (\u0394G<sup>#<\/sup>) was calculated by employing equation, \u0394G<sup>#<\/sup>&nbsp;= \u0394H<sup>#<\/sup>&nbsp;\u2212 T\u0394S<sup>#<\/sup>&nbsp;. These values have been estimated with standard deviation to be as \u2206H<sup>#<\/sup>=15.92\u00b10.42 kJ\/mol, and \u2206<sup>#<\/sup>&nbsp;= -73.85\u00b11.97 J\/mol.K and \u0394G<sup>#<\/sup>&nbsp;= 37.93\u00b1 0.78 kJ\/mol at 298K. The positive values of \u2206H<sup>#<\/sup>&nbsp;and \u2206G<sup>#<\/sup>&nbsp;recommend the redox reaction to be an endothermic reaction.<\/p>\n<\/div>\n<div class=\"item abstract\">\n<div>\n<h3 class=\"label\">How to Cite this paper?<\/h3>\n<div class=\"csl-entry\">\n<p><strong>APA-7 Style<\/strong><br>Summer, S., Ansari, S., Qamar, N., Naqvi, I.I. (2017). Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 7(1-4), 17-19<\/a>. https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04<\/p>\n<p><strong>ACS Style<\/strong><br>Summer, S.; Ansari, S.; Qamar, N.; Naqvi, I.I. Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04\" target=\"_blank\" rel=\"noopener\"><em>Pak. J. Chem.<\/em>&nbsp;2017, 7, 17-19<\/a>. https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04<\/p>\n<p><strong>AMA Style<\/strong><br>Summer S, Ansari S, Qamar N, Naqvi II. Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>. 2017; 7(1-4): 17-19<\/a>. https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04<\/p>\n<p><strong>Chicago\/Turabian Style<\/strong><br>Summer, S., S. Ansari, N. Qamar, and I. I. Naqvi. 2017. &#8220;Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate&#8221;&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>&nbsp;7, no. 1-4: 17-19<\/a>. https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04<\/p>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"item copyright\">\n<p><a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\"><img decoding=\"async\" src=\"https:\/\/i.creativecommons.org\/l\/by\/4.0\/88x31.png\" alt=\"Creative Commons License\"><\/a><\/p>\n<p>This work is licensed under a&nbsp;<a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\">Creative Commons Attribution 4.0 International License<\/a>.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/article>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-bcb17bb e-con-full e-flex e-con e-child\" data-id=\"bcb17bb\" data-element_type=\"container\">\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Research Article | Open Access Volume 7 | Issue 1-4 |&nbsp;https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04 Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate S. Summer Department of Chemistry, Jinnah University for Women, V-C, Nazimabad, Karachi, Pakistan S. Ansari Department of Chemistry, Jinnah University for Women, V-C, Nazimabad, Karachi, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-2864","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate - Pakistan Journal of Chemistry<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2017\/12\/31\/pjc-0417\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate - Pakistan Journal of Chemistry\" \/>\n<meta property=\"og:description\" content=\"Research Article | Open Access Volume 7 | Issue 1-4 |&nbsp;https:\/\/doi.org\/10.15228\/2017.v07.i01-4.p04 Effect of Temperature and Evaluation of Thermodynamic Parameters for Ag(I) Catalyzed Oxidation of Tris (2, 2\u00b4-bipyridine)Fe(II)complex ion by peroxodisulfate S. 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