{"id":2735,"date":"2015-04-01T12:39:00","date_gmt":"2015-04-01T12:39:00","guid":{"rendered":"https:\/\/chempublishers.com\/pjc\/?p=2735"},"modified":"2025-06-14T05:25:38","modified_gmt":"2025-06-14T05:25:38","slug":"pjc-0115","status":"publish","type":"post","link":"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2015\/04\/01\/pjc-0115\/","title":{"rendered":"Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"2735\" class=\"elementor elementor-2735\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-e18425a e-flex e-con-boxed e-con e-parent\" data-id=\"e18425a\" data-element_type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-7ab06ef e-con-full e-flex e-con e-child\" data-id=\"7ab06ef\" data-element_type=\"container\">\n\t\t\t\t<div class=\"elementor-element elementor-element-8585b1c elementor-widget elementor-widget-text-editor\" data-id=\"8585b1c\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<table border=\"0\" width=\"100%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td>\n<div><strong>Research Article | Open Access<\/strong><\/div>\n<div class=\"item doi\"><span class=\"value\">Volume 5 | Issue 1 |&nbsp; <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2024\/12\/PJC-v05.i01.p01.pdf\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.15228\/2015.v05.i01.p01<\/a><\/span><\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate<\/h4>\n<h4><strong><b>R. Naz<\/b><\/strong><\/h4>\n<p>Department of Chemistry, University of Karachi, 75270, Karachi, Pakistan.<\/p>\n<h4><strong><b>R. Azmat&nbsp;<\/b><\/strong><\/h4>\n<p>Department of Chemistry, University of Karachi, 75270, Karachi, Pakistan.<\/p>\n<h4><strong><b>N. Qamar<\/b><\/strong><\/h4>\n<p>Department of Chemistry, Jinnah University for Women, 74600 Karachi, Pakistan<\/p>\n<h4><strong><b>H. Jaffery<\/b><\/strong><\/h4>\n<p>Department of Chemistry, University of Karachi, 75270, Karachi, Pakistan.<\/p>\n<h4><strong><b>S. Nisar<\/b><\/strong><\/h4>\n<p>Department of Chemistry, University of Karachi, 75270, Karachi, Pakistan.<\/p>\n<table border=\"0\" width=\"93%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td align=\"center\" valign=\"top\"><strong>Received<\/strong><br>06 Mar, 2015<\/td>\n<td align=\"center\" valign=\"top\"><strong>Accepted<\/strong><br>21 Sep, 2015<\/td>\n<td align=\"center\" valign=\"top\"><strong>Published<\/strong><br>06 Dec, 2015<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p><strong><u><b>ABSTRACT:<\/b><\/u><\/strong><\/p>\n<p>A comparative kinetic and mechanistic study of oxidation of \u03b2-Cyclodextrin (\u03b2-CD) by Potassium Dichromate (K2Cr2O7) in presence of aqueous H2SO4 medium was monitored at \u03bbmax 350 nm spectrophotometrically. The oxidation reaction follows first order kinetics with respect to [\u03b2-CD] and [Cr2O7 -2 ] and markedly increased by increasing [H+ ]. The slow reaction was accelerated with Fe (III) as a catalyst that enhances the rate significantly. The results of varying temperature were used to compute different activation parameters. The values of activation energy Ea were 37.70KJ mol-1 for catalysed and 50.183 KJ mol-1 for uncatalysed reactions. These clearly indicate that Fe (III) greatly reduced the activation barrier thereby increases the rate of reaction. Oxidation product results due to the oxidation of -CH2OH group present on each glucose monomer of \u03b2-CD.A mechanism consistent with kinetic and thermodynamic data is also proposed that involves two-electron reduction of Cr (VI).<\/p>\n<h3><strong><b>How to Cite this paper?<\/b><\/strong><\/h3>\n<p><strong><b>APA-7 Style<\/b><\/strong><br>Naz, R., Azmat, R., Qamar, N., Jaffery, H., &amp; Nisar, S. (2015). Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate.&nbsp;<em><i>Pakistan Journal of Chemistry<\/i><\/em>,&nbsp;<em><i>5<\/i><\/em>(1). https:\/\/doi.org\/10.15228\/2015.v05.i01.p01<\/p>\n<p><strong><b>ACS Style<\/b><\/strong><br>Naz, R., Azmat, R., Qamar, N., Jaffery, H. and Nisar, S., 2015. Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate.&nbsp;<em><i>Pakistan Journal of Chemistry<\/i><\/em>,&nbsp;<em><i>5<\/i><\/em>(1). https:\/\/doi.org\/10.15228\/2015.v05.i01.p01<\/p>\n<p><strong><b>AMA Style<\/b><\/strong><br>Naz R, Azmat R, Qamar N, Jaffery H, Nisar S. Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate. Pakistan Journal of Chemistry. 2015 Mar 1;5(1). https:\/\/doi.org\/10.15228\/2015.v05.i01.p01<\/p>\n<p><strong><b>Chicago\/Turabian Style<\/b><\/strong><br>Naz, R., R. Azmat, N. Qamar, H. Jaffery, and S. Nisar. &#8220;Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate.&#8221;&nbsp;<em><i>Pakistan Journal of Chemistry<\/i><\/em>&nbsp;5, no. 1 (2015). https:\/\/doi.org\/10.15228\/2015.v05.i01.p01<\/p>\n<p><a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\"><img decoding=\"async\" src=\"https:\/\/i.creativecommons.org\/l\/by\/4.0\/88x31.png\" alt=\"Creative Commons License\"><\/a><\/p>\n<p>This work is licensed under a&nbsp;<a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\"><u>Creative Commons Attribution 4.0 International License<\/u><\/a>.<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-2e2b916 e-con-full e-flex e-con e-child\" data-id=\"2e2b916\" data-element_type=\"container\">\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Research Article | Open Access Volume 5 | Issue 1 |&nbsp; https:\/\/doi.org\/10.15228\/2015.v05.i01.p01 Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate R. Naz Department of Chemistry, University of Karachi, 75270, Karachi, Pakistan. R. Azmat&nbsp; Department of Chemistry, University of Karachi, 75270, Karachi, Pakistan. N. Qamar Department of Chemistry, Jinnah University for Women, [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-2735","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate - Pakistan Journal of Chemistry<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2015\/04\/01\/pjc-0115\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate - Pakistan Journal of Chemistry\" \/>\n<meta property=\"og:description\" content=\"Research Article | Open Access Volume 5 | Issue 1 |&nbsp; https:\/\/doi.org\/10.15228\/2015.v05.i01.p01 Comparative Kinetic and Mechanistic Study of Oxidation of \u03b2-Cyclodextrin by Potassium Dichromate R. 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