{"id":2584,"date":"2014-12-30T05:18:00","date_gmt":"2014-12-30T05:18:00","guid":{"rendered":"https:\/\/chempublishers.com\/pjc\/?p=2584"},"modified":"2025-06-14T06:52:14","modified_gmt":"2025-06-14T06:52:14","slug":"pjc-2614","status":"publish","type":"post","link":"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2014\/12\/30\/pjc-2614\/","title":{"rendered":"Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"2584\" class=\"elementor elementor-2584\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-2448f49 e-flex e-con-boxed e-con e-parent\" data-id=\"2448f49\" data-element_type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-fb4ce4a e-con-full e-flex e-con e-child\" data-id=\"fb4ce4a\" data-element_type=\"container\">\n\t\t\t\t<div class=\"elementor-element elementor-element-2f80f44 elementor-widget elementor-widget-text-editor\" data-id=\"2f80f44\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<table border=\"0\" width=\"100%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td>\n<div><strong>Research Article | Open Access<\/strong><\/div>\n<div class=\"item doi\"><span class=\"value\">Volume 4 | Issue 4 |&nbsp;<a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2024\/12\/PJC-v04.i04.p05.pdf\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.15228\/2014.v04.i04.p05<\/a><\/span><\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<article class=\"obj_article_details\">\n<h4>Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes<\/h4>\n<div class=\"row\">\n<div class=\"main_entry\">\n<p><span class=\"name\">M. Ameen<\/span><\/p>\n<p>Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan<\/p>\n<p><span class=\"name\">S. R. Gilani<\/span><\/p>\n<p>Nano Science and Catalysis Division, Nation Centre for Physics, Islamabad, Pakistan<\/p>\n<p><span class=\"name\">A. Naseer<\/span><\/p>\n<p>Nano Science and Catalysis Division, Nation Centre for Physics, Islamabad, Pakistan<\/p>\n<p><span class=\"name\">I. Shoukat<\/span><\/p>\n<p>Nano Science and Catalysis Division, Nation Centre for Physics, Islamabad, Pakistan<\/p>\n<p><span class=\"name\">S.D. Ali<\/span><\/p>\n<p>Nano Science and Catalysis Division, Nation Centre for Physics, Islamabad, Pakistan<\/p>\n<div class=\"item abstract\">\n<p class=\"ql-align-justify\">Novel oxalato-bridged binuclear metal {Cu(II) and Zn(II)} complexes; [{(L<sub>1<\/sub>)M(II)}<sub>2<\/sub>OX] (L<sub>1<\/sub>= 2-({2-hydroxy-5-[(4- nitrophenyl)diazenyl]benzylidene}amino)benzoic acid, OX = oxalate) and [{(L<sub>2<\/sub>)M(II)}<sub>2<\/sub>OX], (L<sub>2<\/sub>&nbsp;= 2-{[(2- hydroxyphenyl)imino]methyl}-4-[(4-nitrophenyl)diazenyl] phenol, OX = oxalate) were synthesized. Azo anils and corresponding Metal {Cu((II) and Zn(II)} complexes were characterised by Elemental Combustion System, Atomic Absorption Spectroscopy (AAS), Fourier Transform Infrared (FTIR) spectroscopy, UV-Visible, Spectroscopy and&nbsp;<sup>13<\/sup>C<sup>1<\/sup>H-Nuclear Magnetic Resonance spectroscopy. Elemental Analyses, FTIR and UV-Vis were used for structural characterization of metal complexes and distorted octahedral geometry for M(II) complexes came into being. The antibacterial activities of azo anils ligands, oxalate ion, CuCl<sub>2<\/sub>.2H<sub>2<\/sub>O, Zn(CH<sub>3<\/sub>COO)<sub>2<\/sub>.2H<sub>2<\/sub>O and metal {Cu(II) and Zn(II)} complexes against gram-positive (Bacillis subtilis) and gramnegative (Escherichia coli) were evaluated. The antibacterial activities were performed to asses inhibition potential of ligand and their metal {Cu(II) and Zn(II)} complexes. The results revealed that antibacterial activities of azo anils become more pronounced when free ligands were coordinated to central metal atom.<\/p>\n<\/div>\n<div class=\"item abstract\">\n<div>\n<h3 class=\"label\">How to Cite this paper?<\/h3>\n<div class=\"csl-entry\">\n<p><strong>APA-7 Style<\/strong><br>Ameen, M., Gilani, S.R., Naseer, A., Shoukat, ., Ali, S.D. (2014). Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2014.v04.i04.p05\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 4(4), 190-197<\/a>. https:\/\/doi.org\/10.15228\/2014.v04.i04.p05<\/p>\n<p><strong>ACS Style<\/strong><br>Ameen, M.; Gilani, S.R.; Naseer, A.; Shoukat, .; Ali, S.D. Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2014.v04.i04.p05\" target=\"_blank\" rel=\"noopener\"><em>Pak. J. Chem.<\/em>&nbsp;2014, 4, 190-197<\/a>. https:\/\/doi.org\/10.15228\/2014.v04.i04.p05<\/p>\n<p><strong>AMA Style<\/strong><br>Ameen M, Gilani SR, Naseer A, Shoukat , Ali SD. Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2014.v04.i04.p05\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>. 2014; 4(4): 190-197<\/a>. https:\/\/doi.org\/10.15228\/2014.v04.i04.p05<\/p>\n<p><strong>Chicago\/Turabian Style<\/strong><br>Ameen, M., S. R. Gilani, A. Naseer, I. Shoukat, and S. D. Ali. 2014. &#8220;Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes&#8221;&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2014.v04.i04.p05\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>&nbsp;4, no. 4: 190-197<\/a>. https:\/\/doi.org\/10.15228\/2014.v04.i04.p05<\/p>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"item copyright\">\n<p><a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\"><img decoding=\"async\" src=\"https:\/\/i.creativecommons.org\/l\/by\/4.0\/88x31.png\" alt=\"Creative Commons License\"><\/a><\/p>\n<p>This work is licensed under a&nbsp;<a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\">Creative Commons Attribution 4.0 International License<\/a>.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/article>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-210555f e-con-full e-flex e-con e-child\" data-id=\"210555f\" data-element_type=\"container\">\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Research Article | Open Access Volume 4 | Issue 4 |&nbsp;https:\/\/doi.org\/10.15228\/2014.v04.i04.p05 Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes M. Ameen Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan S. R. Gilani Nano Science and Catalysis Division, Nation Centre for Physics, Islamabad, Pakistan A. Naseer Nano [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-2584","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes - Pakistan Journal of Chemistry<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2014\/12\/30\/pjc-2614\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes - Pakistan Journal of Chemistry\" \/>\n<meta property=\"og:description\" content=\"Research Article | Open Access Volume 4 | Issue 4 |&nbsp;https:\/\/doi.org\/10.15228\/2014.v04.i04.p05 Antibacterial Activities of Newly Synthesized Azo Anils And its Oxalato-Bridged Binuclear {Cu(II) and Zn(II)} Complexes M. 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