{"id":1532,"date":"2013-03-30T11:46:00","date_gmt":"2013-03-30T11:46:00","guid":{"rendered":"https:\/\/chempublishers.sourcingoutfit.com\/?p=1532"},"modified":"2025-06-14T06:59:44","modified_gmt":"2025-06-14T06:59:44","slug":"pjc-0813","status":"publish","type":"post","link":"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2013\/03\/30\/pjc-0813\/","title":{"rendered":"A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment"},"content":{"rendered":"\t\t<div data-elementor-type=\"wp-post\" data-elementor-id=\"1532\" class=\"elementor elementor-1532\" data-elementor-post-type=\"post\">\n\t\t\t\t<div class=\"elementor-element elementor-element-2ad6a1b e-flex e-con-boxed e-con e-parent\" data-id=\"2ad6a1b\" data-element_type=\"container\">\n\t\t\t\t\t<div class=\"e-con-inner\">\n\t\t<div class=\"elementor-element elementor-element-cc45329 e-con-full e-flex e-con e-child\" data-id=\"cc45329\" data-element_type=\"container\">\n\t\t\t\t<div class=\"elementor-element elementor-element-44e4157 elementor-widget elementor-widget-text-editor\" data-id=\"44e4157\" data-element_type=\"widget\" data-widget_type=\"text-editor.default\">\n\t\t\t\t<div class=\"elementor-widget-container\">\n\t\t\t\t\t\t\t\t\t<table border=\"0\" width=\"100%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td>\n<div><strong>Short Communication | Open Access<\/strong><\/div>\n<div class=\"item doi\"><span class=\"value\">Volume 3 | Issue 1 | Paper 08 |&nbsp; <a href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/wp-content\/uploads\/sites\/2\/2025\/01\/PJC-v03.i01.p08.pdf\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.15228\/2013.v03.i01.p08<\/a><\/span><\/div>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<article class=\"obj_article_details\">\n<h4>A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment<\/h4>\n<div class=\"row\">\n<h4 class=\"main_entry\"><span class=\"name\">Rafia Azmat<\/span><\/h4>\n<p>Department of Chemistry, University of Karachi, Pakistan<\/p>\n<table border=\"0\" width=\"93%\" cellspacing=\"0\" cellpadding=\"0\" align=\"center\">\n<tbody>\n<tr>\n<td align=\"center\" valign=\"top\"><strong>Received<\/strong><br>10 Apr, 2013<\/td>\n<td align=\"center\" valign=\"top\"><strong>Accepted<\/strong><br>12 Oct, 2013<\/td>\n<td align=\"center\" valign=\"top\"><strong>Published<\/strong><br>14 Nov, 2013<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<div class=\"item abstract\">\n<p align=\"justify\">ABSTRACT:<\/p>\n<p class=\"ql-align-justify\">In the study of chemical kinetics, usually solvent effect was explained to show the consequences on rate of reaction theoretically which is difficult to understand for under graduate students. The blue bottle experiment as a \u201cone day activity\u201d can be used to explain well visually the solvent effect through demonstration of color change. Kinetics of reduction of methylene green by sucrose and mannose in pure and aqueous methanol medium in presence of NaOH has been investigated for demonstration of solvent effect. The two sugars sucrose and mannose were selected for the experiment those acts as a reducing agents in a basic solution and reduces the methylene green into colorless form. The progress of this reduction reaction was followed by the color changes that the methylene green goes through in variable percentage of alcohol. When the bottle is shaken the oxygen in the air mixes with the solution and oxidizes the methylene green back to its intermediate state (purple). The color of the solution will gradually change and become purple (intermediate) and then colorless in 5-10% methanol but in pure methanol color transition were Blue-&gt; purple-&gt; pink indicate the color due to the alcoholic medium. It was observed that increase in percentage in the solvent composition decrease the rate of reduction. The pink color continues due to alcoholic medium which may be attributed with the solvent effect. The observed variation in reading with solvent compositions has been interpreted in terms of interactions of media with the reacting species and the transitions state involved in this reaction.<\/p>\n<\/div>\n<div class=\"item abstract\">\n<div>\n<h3 class=\"label\">How to Cite this paper?<\/h3>\n<div class=\"csl-entry\">\n<p><strong>APA-7 Style<\/strong><br>Azmat, R. (2013). A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2013.v03.i01.p08\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>, 3(1), 45-47<\/a>. https:\/\/doi.org\/10.15228\/2013.v03.i01.p08<\/p>\n<p><strong>ACS Style<\/strong><br>Azmat, R. A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2013.v03.i01.p08\" target=\"_blank\" rel=\"noopener\"><em>Pak. J. Chem.<\/em>&nbsp;2013, 3, 45-47<\/a>. https:\/\/doi.org\/10.15228\/2013.v03.i01.p08<\/p>\n<p><strong>AMA Style<\/strong><br>Azmat R. A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment.&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2013.v03.i01.p08\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>. 2013; 3(1): 45-47<\/a>. https:\/\/doi.org\/10.15228\/2013.v03.i01.p08<\/p>\n<p><strong>Chicago\/Turabian Style<\/strong><br>Azmat, Rafia. 2013. &#8220;A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment&#8221;&nbsp;<a href=\"https:\/\/doi.org\/10.15228\/2013.v03.i01.p08\" target=\"_blank\" rel=\"noopener\"><em>Pakistan Journal of Chemistry<\/em>&nbsp;3, no. 1: 45-47<\/a>. https:\/\/doi.org\/10.15228\/2013.v03.i01.p08<\/p>\n<\/div>\n<\/div>\n<\/div>\n<div class=\"item copyright\">\n<p><a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\"><img decoding=\"async\" src=\"https:\/\/i.creativecommons.org\/l\/by\/4.0\/88x31.png\" alt=\"Creative Commons License\"><\/a><\/p>\n<p>This work is licensed under a&nbsp;<a href=\"https:\/\/creativecommons.org\/licenses\/by\/4.0\/\" rel=\"license\">Creative Commons Attribution 4.0 International License<\/a>.<\/p>\n<\/div>\n<\/div>\n<\/article>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t<div class=\"elementor-element elementor-element-660bed0 e-con-full e-flex e-con e-child\" data-id=\"660bed0\" data-element_type=\"container\">\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t","protected":false},"excerpt":{"rendered":"<p>Short Communication | Open Access Volume 3 | Issue 1 | Paper 08 |&nbsp; https:\/\/doi.org\/10.15228\/2013.v03.i01.p08 A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment Rafia Azmat Department of Chemistry, University of Karachi, Pakistan Received10 Apr, 2013 Accepted12 Oct, 2013 Published14 Nov, 2013 ABSTRACT: In the study of chemical kinetics, usually solvent [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-1532","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>A Visual Demonstration of Solvent Effect in Chemical Kinetics through Blue Bottle Experiment - Pakistan Journal of Chemistry<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/chempublishers.com\/Pakistan-journal-of-chemistry\/2013\/03\/30\/pjc-0813\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta 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